Sodium Phosphate In Treated Boiler Water

Need of Boiler Feed water Treatment | Boiler water

Boiler water is the term used specifically to refer to water which is heated inside the actual boiler . Boiler water is provided by the boiler feed water from the boiler as either heated water or steam.. Boiler feed water: The water which directly enters the Boiler. Boiler feed water is made of Makeup water and Return Condensate.. Makeup Water: Make water is the original raw water derived from

What is makeup water in a boiler? | AnswersDrive

Boiler water is the liquid phase of steam within a boiler. The term may also be applied to raw water intended for use in boilers, treated boiler feedwater, steam condensate being returned to a boiler, or boiler blowdown being removed from a boiler.

Power plant chemistry internal water treatment

Tri Sodium Phosphate When it is required to reduce the concentration of NaOH in boiler water mono sodium phosphate and hexa meta phosphate can be used Na2HPo4 + 2NaOH Na3Po4 + 2H2O Na3Po36 + 12NaOH 6 Na3Po4 + 6H2O Monosodium phosphate Sodium hexametaphosphate Umar Farooq Senior Chemist NOMAC SIWEP Shuaibah Jeddah 22

Boiler Water Treatment in Marine Boilers - ShipFever

The quality of boiler water is an integral part of increasing boiler efficiency. Unchecked contaminated boiler water can lead to problems such as corrosion and scale formation. Furthermore, it can also affect its performance, life, and cost of maintenance jeopardizing boiler efficiency; making boiler water treatment a key in the marine industry.

Boiler water treatment - Lenntech

The treatment and conditioning of boiler feed water must satisfy three main objectives:. Continuous heat exchange; Corrosion protection; Production of high quality steam; External treatment is the reduction or removal of impurities from water outside the boiler. In general, external treatment is used when the amount of one or more of the feed water impurities is too high to be tolerated by the

An Introduction to Treatment of Steam Boiler Water

2015-7-14 · boiler water treatment may be added (fed) to the water in the steam drum. A process of either continuous or intermittent surface blowdown is used to maintain the TDS of the boiler water and achieve the optimal operating conditions in the boiler. In some boiler systems, the blowdown water will be discharged to a flash tank, where a lower

Boiler Feedwater Treatment (Part I): Why Water

2015-8-20 · The feedwater (make-up water) from outside needs to be treated for the reduction or removal of impurities by first filtration, and then followed by softening, evaporation, deariation, ion exchange etc. Internal treatment is also required for the conditioning of impurities within the boiler system, to control corrosion, as reactions occur in the

GC3 Specialty Chemicals | GC³ Technical Manual:

Caustic Attack. Caustic attack or, as it is more commonly known, caustic corrosion, is often encountered in phosphate treated boilers in which deposits occur in high heat transfer areas. In particular, boiler water can permeate the porous deposit. When it is coupled with significant heat flux, concentration of the boiler water

Exp 14 Boiler Water 0311 - United States Naval Academy

2020-4-21 · Boiler water is treated with a mixture of Na 2HPO4, commonly called disodium phosphate or DSP, and Na 3PO4, commonly called trisodium phosphate or TSP. This mixture serv es as a buffer to maintain the pH of the boiler water in the region of 10.5. Also, the presence of phosphates causes the precipitation of Mg 2+ and Ca 2+ ions as a soft sludge that

RECOVERY BOILER WATER TREATMENT Figure 2 -

2008-1-4 · present in the boiler water. Internal deposits inhibit both the ability of the heat to leave the tube surface and the ability of the water to reach the tube surface to wash away concen-trating salts. While the bulk boiler water may be noncorro-sive, boiler water can

Boiler Water Treatment - ScienceDirect

Role of water chemistry is very crucial for safe and efficient operation of vital components in feedwater–steam circuit. Proper maintenance of water chemistry helps in minimizing corrosion, deposition, and scaling problems in boiler and turbine and prevents costly shutdown and material replacement. pH, cationic conductivity, iron, copper, chloride, dissolved oxygen, silica, and hydrazine

High-Pressure Steam Cycle and Boiler Water Treatment

2010-8-3 · ULTRAMARINESM HP BWT Program • Drew Marine pioneered the "modified phosphate-pH treatment" – Utilizes disodium orthophosphate and caustic so that no "free caustic" is generated in the boiler water – Sodium to phosphate ratio is approximately 2.75:1 and provides margin of safety for good control of the program – Went into effect in the marine industry in the 1960's and has

Exp 14 Boiler Water 0311 - United States Naval Academy

2020-4-21 · Boiler water is treated with a mixture of Na 2HPO4, commonly called disodium phosphate or DSP, and Na 3PO4, commonly called trisodium phosphate or TSP. This mixture serv es as a buffer to maintain the pH of the boiler water in the region of 10.5. Also, the presence of phosphates causes the precipitation of Mg 2+ and Ca 2+ ions as a soft sludge that

Common Chemicals Used in Boiler Water Treatment -

2020-6-20 · Boiler water treatment is the conditioning and treatment of boiler feed water with the purpose of meeting three objectives. In order for boiler water treatment to be maintained, there must be a continuous heat exchange, protection for high-quality steam, and corrosion protection. Boilers are designed to heat fluid, after which the vaporized or heated fluid will exit the boiler and be used for

Need of Boiler Feed water Treatment | Boiler water

Boiler water is the term used specifically to refer to water which is heated inside the actual boiler . Boiler water is provided by the boiler feed water from the boiler as either heated water or steam.. Boiler feed water: The water which directly enters the Boiler. Boiler feed water is made of Makeup water and Return Condensate.. Makeup Water: Make water is the original raw water derived from

Hot Water Boiler Chemical Guide - ChemWorld

Chemically treating a boiler is very easy, but often overlooked. First, we define a hot water boiler as a boiler that generates minimal steam with no condensate return loss or a boiler that produces no steam at all. Types of Boiler Chemicals for Hot Water Boilers By far the most popular hot water boiler chemical is a sodium nitrite blend. This

BOILER WATER TREATMENT CHEMICALS AND ITS

BOILER WATER TREATMENT CHEMICALS AND ITS COMPOSITION. IF YOU ARE INTERESTED IN BOILER WATER TREATMENTS amp; ITS PURPOSE READ THIS ARTICLE.CLICK HERE. Alkalinity Treatment. For pressures below 20 bar dissolved O 2 in the feed does not cause any serious problems so long as the water is kept alkaline However cold feed should be avoided as this introduces large

The International Association for the Properties of Water

2017-1-11 · The International Association for the Properties of Water and Steam Berlin, Germany September 2008 concentration to boiler water sodium concentration. Mechanical carryover is determined (ppm) for phosphate treated boilers and up to 1 mg/kg (ppm) for NaOH treated boilers. These levels are usually sufficient to

67- External Feed water Treatment Flashcards | Quizlet

a) heating the boiler feed water to between 80 and 105 degrees Celsius before it enters the boiler b) cooling the feed water to between 4 and 16 degrees Celsius c) the addition of sodium chloride to the feed water d) agitating the feed water before it enters the boiler e) the addition of sodium sulphate to the feed water

Essentials for a Sound Boiler Water Treatment Program

2018-8-5 · Boiler Water Treatment . 3 . Water is an excellent heat transfer medium, but it must be properly treated in both steam and hot water systems or serious problems will ensue, robbing energy and reducing the life of the asset.

67- External Feed water Treatment Flashcards | Quizlet

a) heating the boiler feed water to between 80 and 105 degrees Celsius before it enters the boiler b) cooling the feed water to between 4 and 16 degrees Celsius c) the addition of sodium chloride to the feed water d) agitating the feed water before it enters the boiler e) the addition of sodium sulphate to the feed water

Properties of Boiler Water - Marine Engineering

If hydrazine (N 2 H 4) is not used, sodium sulphate (Na 2 SO 4) can be used instead, and the excess should be 30 – 60 ppm.. In cases where other kinds of oxygen binding agents are used, it is recommended that an excess of oxygen binding agents can be measured and indicates that no oxygen has been dissolved in the boiler water.

Boiler amp; Cooling Tower Control Basics - Veolia Water Tech

2015-11-3 · say may show up because the phosphate test can indicate both the combined and uncombined phosphate, and the result will only be lower if appreciable amounts of phosphate sludge are blown down from the boiler. Running filtered and unfiltered phosphate tests on the boiler water will give a better understanding of what is happening.

Boiler Water Treatment - Why is It Important ? - Bright

2020-6-13 · Boiler water quality is of prime concern to all boiler operators. The process of water treatment in boilers is not limited to producing high quality DM water. The stringent water chemistry requirements of Supercritical power plants makes water treatment in boilers a very critical aspect of power plant operation. This necessitates the use of a high quality water treatment system.

phosphate dosing in boiler – Industrial boiler company

2017-7-20 · When calcium phosphate is formed in boiler water of sufficient alkalinity (pH Dosing Presentation 2012 – SlideShare. Dec 11, 2012 Some boiler installations need 3-pump HP dosing systems, asshown .. water treatment) Phosphate Dosing/ Hydrazine Dosing (Boiler Feed Phosphate treatment in the steam drum – Steam Turbine, Steam

Methods and apparatus for monitoring and

1998-5-5 · The methods of the present invention comprise the steps of: a) determining the phosphate content of the boiler system by using, flow injection analysis (FIA); b) determining the pH of the boiler system; c) calculating the sodium to phosphate ratio; and d) controlling the feed rate of at least one water treatment chemical being added to said

Water treatment - ScienceDirect

At working pressures above 1.38 to 1.73 MPa or 13.8 to 17.3 bar (200 to 250 psi), the decomposition of Na 2 CO 3 is usually too great to maintain the required concentration of carbonate in the boiler water, and sodium phosphate is used instead, since the phosphate ion (PO 4 3 −) is stable at all boiler temperatures, while calcium phosphate is

Characteristics of boiler feedwater - Lenntech

Feed-water purity requirements therefore can vary widely. A low-pressure fire-tube boiler can usually tolerate high feed-water hardness with proper treatment while virtually all impurities must be removed from water used in some modern, high-pressure boilers. Only relatively wide ranges can be given as to maximum levels of alkalis, salt, silica

Feed water: Why water Treatment is Necessary for

Feed water: Why water Treatment is Necessary for Boiler Contents Water for Boilers Impurities in Water Boiler feedwater Purity requirements of feedwater Boiler Deposits Corrosion Boiler water carryover Water for boilers All natural waters contain varying amounts of suspended and dissolved matters as well as dissolved gases. The type and amount of impurities in

Table 7-4.Trisodium Phosphate Dosage For Natural

The procedures for determining the chemical treatment Table 7-4.—Trisodium Phosphate Dosage For Natural Circulation Auxiliary Boilers (Trisodium Pbosphate, Dodecahydrate, Na 3 PO 4 12H 2 0) Boiler water Alkalinity epm (meg/L) 0.1 0.095 X = 0.2 0.090 X = 0.3 0.085 X = 0.4 0.080 X = 0.5 0.075 X = 0.6 0.070 X = 0.7 0.065 X = 0.8 0.060 X = 0.9 0

Boiler water treatment - Lenntech

The treatment and conditioning of boiler feed water must satisfy three main objectives:. Continuous heat exchange; Corrosion protection; Production of high quality steam; External treatment is the reduction or removal of impurities from water outside the boiler. In general, external treatment is used when the amount of one or more of the feed water impurities is too high to be tolerated by the

Phosphate attack as caustic corrosion in high-pressure

2020-5-22 · This paper discusses sodium phosphate compounds, notably trisodium and disodium phosphate which have been used for years at many fossil-fired power plants for boiler water treatment. The principal purpose is to buffer the boiler water at a suitable pH while adding a compound, PO{sub 4}, which reacts with contaminants to form a non-adherent sludge.

Determination of Salt Component Concentrations in

Implementation of automatic water chemistry control at power units of thermal power stations (TPS) is hindered by the unavailability of analyzers required for monitoring certain standardized characteristics of the coolant. Important characteristics include salt content and ammonia concentration in the feedwater and salt content and phosphate concentration in the boiler water.

Section 3 - Module 10: Internal Water Treatment for

1 Force the hardness in the water to come out of solution by feeding sulphite to the boiler water 2 Treat the suspended solids in the boiler water with lignins 3 Remove suspended solids from the boiler water through blow off 4 Feed soda ash, caustic soda or sodium phosphate to precipitate solids in the boiler water A ) 1,2,3 B ) 1,2,4 C ) 1,3,4

Critical HRSG | Power Engineering

All cooling water contains sodium, and it is a very easy element to monitor on-line. With a tight condenser, sodium levels in the condensate should be very low (lt;2 ppb), and in many cases less

5-2 Recovery Boiler Water Treatment - TAPPI

2008-1-4 · Recovery Boiler Water Treatment January 2008 Presented By Sheppard T. Powell Associates, LLC Treated Makeup S S S S S S S S S S S Usually Operated As A Grab Sample Point Condensate Phosphate Effect on Boiler Water pH Sodium-To-Phosphate Molar Ratio Blowdown Phosphate, mg/L p H NaOH TSP DSP (MSP) 3 . 0 2 . 6 2 . 4 2. 2 . 1

Understand the importance of water/steam chemistry

Like feed-water chemistry, boiler water chemistry has undergone a considerable evolution over the past two to three decades. For decades, phosphate programs have been the workhorse of many treatment programs. Tri-sodium phosphate provides alkalinity beyond that of ammonia. Na 3 PO 4 + H 2 O → NaOH + NaH 2 PO 4

Sodium Sulphite Boiler Water Oxygen Scavenger

Sodium sulphite boiler water oxygen scavenger that is an ideal treatment for both low and medium pressure steam boilers. Accepta 2326 rapidly reacts with oxygen ensuring efficient protection of feedlines and boilers from corrosion and enhancing protection against caustic embrittlement

Feed water: Why water Treatment is Necessary for

Feed water: Why water Treatment is Necessary for Boiler Contents Water for Boilers Impurities in Water Boiler feedwater Purity requirements of feedwater Boiler Deposits Corrosion Boiler water carryover Water for boilers All natural waters contain varying amounts of suspended and dissolved matters as well as dissolved gases. The type and amount of impurities in

Boiler Water Tests | Viking Water Technology, Inc.

To a small extent, phosphate also helps prevent boiler corrosion by forming a protective iron phosphate coating on the boiler metal. Sulfite Test. Sulfite is added to boilers to remove dissolved oxygen, which causes severe pitting corrosion. Theoretically, it takes about 8 ppm of sodium

Monosodium phosphate | NaH2PO4 - PubChem

To determine whether phosphate supplementation, started soon after birth in adequate quantity, would prevent rickets in very low birth weight infants with prenatal deficiency of phosphate, 40 neonates were given an initial dose of 50 mg/day of phosphate administered as a mixture of 189 g of sodium phosphate dibasic (disodium hydrogen phosphate) and 82 g of sodium phosphate monobasic (sodium

Treatment of boiler feed water - NARRAGANSETT

The resultant solution Is proportioned mechanically to the water softener so that for each 100,000 pounds of Water treated, 2.759 pounds of di-sodium phosphate, 0.282 pound of caustic soda, and 0.028 pound of ferric sulphate are added. The weights of chemicals specified to be added produce a solution having a pH value of approximately 11.2.

Boiler Water Treatment – PROWATER LTD

Boiler sludge concentrations created by coagulation treatment may be avoided by sodium phosphate treatment when water hardness is less than 60 mg/L. With adequate alkalinity, addition of sodium phosphate produces an insoluble precipitate of hydroxyapatite with magnesium hydroxide and magnesium and calcium silicates.

Using of congruent phosphate as equilibrium

Phosphate concentration-pH of boiler water when using coordinated phosphate Na/PO 4 ratio equal 3.0. Conductivity and pH of boiler water when using tri-sodium phosphate. +1

What is makeup water in a boiler? | AnswersDrive

Boiler water is the liquid phase of steam within a boiler. The term may also be applied to raw water intended for use in boilers, treated boiler feedwater, steam condensate being returned to a boiler, or boiler blowdown being removed from a boiler.

Methods and apparatus for monitoring and

1998-5-5 · The methods of the present invention comprise the steps of: a) determining the phosphate content of the boiler system by using, flow injection analysis (FIA); b) determining the pH of the boiler system; c) calculating the sodium to phosphate ratio; and d) controlling the feed rate of at least one water treatment chemical being added to said

Water treatment of steam boilers - LinkedIn SlideShare

To maintain a phosphate level of 60 ppm, the required sodium hexa meta phosphate is 4.36 lbs/day (Refer example 6) So total hexa meta phosphate required = 3.45 + 4.36 = 7.81 lbs/day Determination of Caustic Soda required The boiler water hydroxyl alkalinity should be maintained between 20 – 200 ppm to avoid corrosion and magnesium phosphate

Boiler Water Treatment - Association of Water Technologies

Boiler Water Treatment –Preheat Boiler Feed (Atmospheric Feed Water Tank) •195° - 205°F (0.1 – 1 ppm Oxygen) – Oxygen content is based on water temperature, so this tank has to be treated for oxygen before the system can mechanically deaerate. At 150°F Sodium Sulfite has

Water Treatment, Cycle Chemistry, Boiler Operation and

2009-2-27 · Boiler water (BW) is the water circulating within the boiler. It consists of concentrated BFW. 2.3 Definition of Chemical Operation Modes Solid alkaline treatment is defined as the dosing of non-volatile, solid alkalising agents like tri-sodium or tri-potassium phosphate or caustic soda (sodium hydroxide) to adjust the correct pH in BW.

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